SECFit

Top  Previous  Next

Using either SEC or GPS the lab can give a curve with information on the distribution of a polymer sample.

However this curve has to be integrated in order to get the distribution data. At the same time this curve will typical have a large number of points, maybe around 1000 so a smaller distribution with the same shape is needed to perform calculations.

 

This function lets the user integrate a SEC/GPS curve and at the same time generate a distribution of a wanted size.

The integration method is Trapeze giving N-1 pseudo components.

 

To use the function use either the Distribution wizard or the calculation wizard.

 

The wizard prepares a range where the user can enter the SEC data. The routine will try to read all the cells but only the cells with a valid double in both cells are used.

 

Input

Argument

Type

Optional

Description

 

SECData

Range of double

No

2 columns and a number of rows with the SEC/GPS information.

Column 1: Log10 to the molar mass in units g/mole

Column 2: The derivative obtained in the lab.

Size

C# : int

No

Number of pseudo components in the second distribution.

Mn

C# : object

(Expect a double)

Yes

The value of Mn obtained in the lab.

The value given here is only used for comparison with integrated value

Mw

C# : object

(Expect a double)

Yes

The value of Mw obtained in the lab.

The value given here is only used for comparison with integrated value

Mz

C# : object

(Expect a double)

Yes

The value of Mz obtained in the lab.

The value given here is only used for comparison with integrated value

ProjectSheet

C#: object

Yes

Lets the user set the project sheet to use.

See here for more information

AdvVLXE

C# : object

Yes

Advanced used. Reserved for use by VLXE.

AdvUser

C# : object

Yes

Advanced used. Reserved for the user. For example it can be used to force the function update.

 

 

 

Extra

This function is defined in C# as:

public Object[,] SECFit(Range SECData, int Size, [In, Optional] object Mn, [In, Optional] object Mw, [In, Optional] object Mz, [In, Optional] object AdvVLXE, [In, Optional] object AdvUser)

 

Below is a screen dump where some data has been generated and a smaller distribution with 100 pseudo components has been

generated that match the experimental data.

 

SEC